McElroy, Michael B.

Severe wintertime PM_2.5 pollution in Beijing has been receiving increasing worldwide attention, yet the decadal variations remain relatively unexplored. Combining field measurements and model simulations, we quantified the relative influences of anthropogenic emissions and meteorological conditions on PM_2.5 concentrations in Beijing over the winters of 2002–2016. Between the winters of 2011 and 2016, stringent emission control measures resulted in a 21 % decrease in mean mass concentrations of PM_2.5 in Beijing, with 7 fewer haze days per winter on average. Given the overestimation of PM_2.5 by the model, the effectiveness of stringent emission control measures might have been slightly overstated. With fixed emissions, meteorological conditions over the study period would have led to an increase in haze in Beijing, but the strict emission control measures have suppressed the unfavorable influences of the recent climate. The unfavorable meteorological conditions are attributed to the weakening of the East Asia winter monsoon associated particularly with an increase in pressure associated with the Aleutian Low.

Nitrate and sulfate are two key components of airborne particulate matter (PM). While multiple formation mechanisms have been proposed for sulfate, current air quality models commonly underestimate its concentrations and mass fractions during northern China winter haze events. On the other hand, current models usually overestimate the mass fractions of nitrate. Very recently, laboratory studies have proposed that nitrous acid (N(III)) produced by particulate nitrate photolysis can oxidize sulfur dioxide to produce sulfate. Here, for the first time, we parameterize this heterogeneous mechanism into the state-of-the-art Community Multi-scale Air Quality (CMAQ) model and quantify its contributions to sulfate formation. We find that the significance of this mechanism mainly depends on the enhancement effects (by 1–3 orders of magnitude as suggested by the available experimental studies) of nitrate photolysis rate constants in aerosol liquid water compared to that in the gas phase. Comparisons between model simulations and in-situ observations in Beijing suggest that this pathway can explain about 15% (assuming an enhancement factor (EF) of 10) to 65% (assuming EF = 100) of the model–observation gaps in sulfate concentrations during winter haze. Our study strongly calls for future research on reducing the uncertainty in EF.

China has pledged reduction of carbon dioxide (CO₂) emissions per unit of gross domestic product (GDP) by 60 %–65 % relative to 2005 levels, and to peak carbon emissions overall by 2030. However, the lack of observational data and disagreement among the many available inventories makes it difficult for China to track progress toward these goals and evaluate the efficacy of control measures. To demonstrate the value of atmospheric observations for constraining CO₂ inventories we track the ability of CO₂ concentrations predicted from three different CO₂ inventories to match a unique multi-year continuous record of atmospheric CO₂. Our analysis time window includes the key commitment period for the Paris Agreement (2005) and the Beijing Olympics (2008). One inventory is China-specific and two are spatial subsets of global inventories. The inventories differ in spatial resolution, basis in national or subnational statistics, and reliance on global or China-specific emission factors. We use a unique set of historical atmospheric observations from 2005 to 2009 to evaluate the three CO₂ emissions inventories within China's heavily industrialized and populated northern region accounting for ∼33 %–41 % of national emissions. Each anthropogenic inventory is combined with estimates of biogenic CO₂ within a high-resolution atmospheric transport framework to model the time series of CO₂ observations. To convert the model–observation mismatch from mixing ratio to mass emission rates we distribute it over a region encompassing 90 % of the total surface influence in seasonal (annual) averaged back-trajectory footprints (L_0.90 region). The L_0.90 region roughly corresponds to northern China. Except for the peak growing season, where assessment of anthropogenic emissions is entangled with the strong vegetation signal, we find the China-specific inventory based on subnational data and domestic field studies agrees significantly better with observations than the global inventories at all timescales. Averaged over the study time period, the unscaled China-specific inventory reports substantially larger annual emissions for northern China (30 %) and China as a whole (20 %) than the two unscaled global inventories. Our results, exploiting a robust time series of continuous observations, lend support to the rates and geographic distribution in the China-specific inventory Though even long-term observations at a single site reveal differences among inventories, exploring inventory discrepancy over all of China requires a denser observational network in future efforts to measure and verify CO₂ emissions for China both regionally and nationally. We find that carbon intensity in the northern China region has decreased by 47 % from 2005 to 2009, from approximately 4 kg of CO₂ per USD (note that all references to USD in this paper refer to USD adjusted for purchasing power parity, PPP) in 2005 to about 2 kg of CO₂ per USD in 2009 (Fig. 9c). However, the corresponding 18 % increase in absolute emissions over the same time period affirms a critical point that carbon intensity targets in emerging economies can be at odds with making real climate progress. Our results provide an important quantification of model–observation mismatch, supporting the increased use and development of China-specific inventories in tracking China's progress as a whole towards reducing emissions. We emphasize that this work presents a methodology for extending the analysis to other inventories and is intended to be a comparison of a subset of anthropogenic CO₂ emissions rates from inventories that were readily available at the time this research began. For this study's analysis time period, there was not enough spatially distinct observational data to conduct an optimization of the inventories. The primary intent of the comparisons presented here is not to judge specific inventories, but to demonstrate that even a single site with a long record of high-time-resolution observations can identify major differences among inventories that manifest as biases in the model–data comparison. This study provides a baseline analysis for evaluating emissions from a small but important region within China, as well a guide for determining optimal locations for future ground-based measurement sites.

Understanding how internal atmospheric variability affects Greenland Ice Sheet (GrIS) summertime melting would improve understanding of future sea level rise. We analyze the Community Earth System Model Large Ensemble (CESM‐LE) over 1951‐2000 and 2051‐2100. We find that internal variability dominates the forced response on short timescales (~20 years) and that the area impacted by internal variability grows in the future, connecting internal variability and climate change. Unlike prior studies, we do not assume specific patterns of internal variability to affect GrIS melting, but derive them from Maximum Covariance Analysis. We find that the North Atlantic Oscillation (NAO) is the major source of internal atmospheric variability associated with GrIS melt conditions in CESM‐LE and reanalysis, with the positive phase (NAO+) linked to widespread cooling over the ice sheet. CESM‐LE and CMIP5 project an increase in the frequency of NAO+ events, suggesting a negative feedback to the GrIS under future climate change.

This paper considers options for a future Indian power economy in which renewables, wind and solar, could meet 80% of anticipated 2040 power demand supplanting the country’s current reliance on coal. Using a cost optimization model, here we show that renewables could provide a source of power cheaper or at least competitive with what could be supplied using fossil-based alternatives. The ancillary advantage would be a significant reduction in India’s future power sector related emissions of CO₂. Using a model in which prices for wind turbines and solar PV systems are assumed to continue their current decreasing trend, we conclude that an investment in renewables at a level consistent with meeting 80% of projected 2040 power demand could result in a reduction of 85% in emissions of CO₂ relative to what might be expected if the power sector were to continue its current coal dominated trajectory.

China has reduced growth in its emissions of greenhouse gases, success attributable in part due to major investments in onshore wind. By comparison, investments in offshore wind have been minor, limited until recently largely by perceptions of cost. Assimilated meteorological data are used here to assess future offshore wind potential for China. Analysis on a provincial basis indicates that the aggregate potential wind resource is 5.4 times larger than current coastal demand for power. Recent experiences with markets both in Europe and the US suggest that potential offshore resources in China could be exploited to cost-competitively provide 1148.3 TWh of energy in a high-cost scenario, 6383.4 TWh in a low-cost option, equivalent to between 36% and 200% of the total coastal energy demand post 2020. The analysis underscores significant benefits for offshore wind for China, with prospects for major reductions greenhouse emissions with ancillary benefits for air quality.

A regional fully coupled meteorology–chemistry model, Weather Research and Forecasting model with Chemistry (WRF-Chem), was employed to study the seasonality of ozone (O₃) pollution and its sources in both China and India. Observations and model results suggest that O₃ in the North China Plain (NCP), Yangtze River Delta (YRD), Pearl River Delta (PRD), and India exhibit distinctive seasonal features, which are linked to the influence of summer monsoons. Through a factor separation approach, we examined the sensitivity of O₃ to individual anthropogenic, biogenic, and biomass burning emissions. We found that summer O₃ formation in China is more sensitive to industrial and biogenic sources than to other source sectors, while the transportation and biogenic sources are more important in all seasons for India. Tagged simulations suggest that local sources play an important role in the formation of the summer O₃ peak in the NCP, but sources from Northwest China should not be neglected to control summer O₃ in the NCP. For the YRD region, prevailing winds and cleaner air from the ocean in summer lead to reduced transport from polluted regions, and the major source region in addition to local sources is Southeast China. For the PRD region, the upwind region is replaced by contributions from polluted PRD as autumn approaches, leading to an autumn peak. The major upwind regions in autumn for the PRD are YRD (11 %) and Southeast China (10 %). For India, sources in North India are more important than sources in the south. These analyses emphasize the relative importance of source sectors and regions as they change with seasons, providing important implications for O₃ control strategies.

China pledges to peak CO₂ emissions by 2030 or sooner under the Paris Agreement to limit global warming to 2 °C or less by the end of the century. By examining CO₂ emissions from 50 Chinese cities over the period 2000–2016, we found a close relationship between per capita emissions and per capita gross domestic product (GDP) for individual cities, following the environmental Kuznets curve, despite diverse trajectories for CO₂ emissions across the cities. Results show that carbon emissions peak for most cities at a per capita GDP (in 2011 purchasing power parity) of around US$21,000 (80% confidence interval: US$19,000 to 22,000). Applying a Monte Carlo approach to simulate the peak of per capita emissions using a Kuznets function based on China’s historical emissions, we project that emissions for China should peak at 13–16 GtCO₂ yr⁻¹ between 2021 and 2025, approximately 5–10 yr ahead of the current Paris target of 2030. We show that the challenges faced by individual types of Chinese cities in realizing low-carbon development differ significantly depending on economic structure, urban form and geographical location.

Realizing the goal of the Paris Agreement to limit global warming to 2 °C by the end of this century will most likely require deployment of carbon-negative technologies. It is particularly important that China, as the world’s top carbon emitter, avoids being locked into carbon-intensive, coal-fired power-generation technologies and undertakes a smooth transition from high- to negative-carbon electricity production. We focus here on deploying a combination of coal and biomass energy to produce electricity in China using an integrated gasification cycle system combined with carbon capture and storage (CBECCS). Such a system will also reduce air pollutant emissions, thus contributing to China’s near-term goal of improving air quality. We evaluate the bus-bar electricity-generation prices for CBECCS with mixing ratios of crop residues varying from 0 to 100%, as well as associated costs for carbon mitigation and cobenefits for air quality. We find that CBECCS systems employing a crop residue ratio of 35% could produce electricity with net-zero life-cycle emissions of greenhouse gases, with a levelized cost of electricity of no more than 9.2 US cents per kilowatt hour. A carbon price of approximately $52.0 per ton would make CBECCS cost-competitive with pulverized coal power plants. Therefore, our results provide critical insights for designing a CBECCS strategy in China to harness near-term air-quality cobenefits while laying the foundation for achieving negative carbon emissions in the long run.

Haze days induced by aerosol pollution in North and East China have posed a persistent and growing problem over the past few decades. These events are particularly threatening to densely-populated cities such as Beijing. While the sources of this pollution are predominantly anthropogenic, natural climate variations may also play a role in allowing for atmospheric conditions conducive to formation of severe haze episodes over populated areas. Here, an investigation is conducted into the effects of changes in global dynamics and emissions on air quality in China’s polluted regions using 35 simulations developed from the Community Earth Systems Model Large Ensemble (CESM LENS) run over the period 1920-2100. It is shown that internal variability significantly modulates aerosol optical depth (AOD) over China; it takes roughly a decade for the forced response to balance the effects from internal variability even in China’s most polluted regions. Random forest regressions are used to accurately model (R² > 0.9) wintertime AOD using just climate oscillations, the month of the year and emissions. How different phases of each oscillation affect aerosol loading are projected using these regressions. AOD responses are identified for each oscillation, with particularly strong responses from El Niño-Southern Oscillation (ENSO) and the Pacific Decadal Oscillation (PDO). As ENSO can be projected a few months in advance and improvements in linear inverse modelling (LIM) may yield a similar predictability for the PDO, results of this study offer opportunities to improve the predictability of China’s severe wintertime haze events, and to inform policy options that could mitigate subsequent health impacts.

Deploying high penetration of variable renewables represents a critical pathway for decarbonizing the power sector. Hydro power (including pumped-hydro), batteries, and fast responding thermal units are essential in providing system flexibility at elevated renewable penetration. How to quantify the merit of flexibility from these sources in accommodating variable renewables, and to evaluate the operational costs considering system flexibility constraints have been central challenges for future power system planning. This paper presents an improved linear formulation of the unit commitment model adopting unit grouping techniques to expedite evaluation of the curtailment of renewables and operational costs for large-scale power systems. All decision variables in this formulation are continuous, and all chronological constraints are formulated subsequently. Tested based on actual data from a regional power system in China, the computational speed of the model is more than 20,000 times faster than the rigorous unit commitment model, with less than 1% difference in results. Hourly simulation for an entire year takes less than 3 min. The results demonstrate strong potential to apply the proposed model to long term planning related issues, such as flexibility assessment, wind curtailment analysis, and operational cost evaluation, which could set a methodological foundation for evaluating the optimal combination of wind, solar and hydro investments.

The chemical mechanisms responsible for rapid sulfate production, an important driver of winter haze formation in northern China, remain unclear. Here, we propose a potentially important heterogeneous hydroxymethanesulfonate (HMS) chemical mechanism. Through analyzing field measurements with aerosol mass spectrometry, we show evidence for a possible significant existence in haze aerosols of organosulfur primarily as HMS, misidentified as sulfate in previous observations. We estimate that HMS can account for up to about one-third of the sulfate concentrations unexplained by current air quality models. Heterogeneous production of HMS by SO₂ and formaldehyde is favored under northern China winter haze conditions due to high aerosol water content, moderately acidic pH values, high gaseous precursor levels, and low temperature. These analyses identify an unappreciated importance of formaldehyde in secondary aerosol formation and call for more research on sources and on the chemistry of formaldehyde in northern China winter.

Construction of carbon-intensive energy infrastructure is well underway under the Belt & Road Initiative (BRI), challenging the global climate target. Regionally abundant solar power could provide an alternative for electricity generation. An integrative spatial model was developed to evaluate the technical potential of solar photovoltaic power. The influence of impacting factors was quantified systematically on an hourly basis. Results suggest that the electricity potential for the BRI region reaches 448.9 PWh annually, 41.3 times the regional demand for electricity in 2016. Tapping 3.7% of the potential through deploying 7.8 TW capacity could satisfy the regional electricity demand projected for 2030, requiring an investment of approximately 11.2 trillion 2017 USD and a commitment in land area of 88,426 km², approximately 0.9% of China’s total. Countries endowed with 70.7% of the overall potential consume only 30.1% of regional electricity. The imbalance underscores the advantage of regional cooperation and investments in interconnected grids.

During recent years, aggressive air pollution mitigation measures in northern China have resulted in considerable changes in gas and aerosol chemical composition. But it is unclear whether aerosol water content and acidity respond to these changes. The two parameters have been shown to affect heterogeneous production of winter haze aerosols. Here, we performed thermodynamic equilibrium modeling using chemical and meteorological data observed in urban Beijing for four recent winter seasons and quantified the changes in the mass growth factor and pH of inorganic aerosols. We focused on high relative humidity (>60%) conditions when submicron particles have been shown to be in the liquid state. From 2014/2015 to 2018/2019, the modeled mass growth factor decreased by about 9%–17% due to changes in aerosol compositions (more nitrate and less sulfate and chloride), and the modeled pH increased by about 0.3–0.4 unit mainly due to rising ammonia. A buffer equation is derived from semivolatile ammonia partitioning, which helps understand the sensitivity of pH to meteorological and chemical variables. The findings provide implications for evaluating the potential chemical feedback in secondary aerosol production and the effectiveness of ammonia control as a measure to alleviate winter haze.

Accurately quantifying the spatiotemporal distribution of the biological component of CO₂ surface–atmosphere exchange is necessary to improve top-down constraints on China's anthropogenic CO₂ emissions. We provide hourly fluxes of CO₂ as net ecosystem exchange (NEE; µmol CO₂ m⁻² s⁻¹) on a 0.25∘×0.25∘" id="MathJax-Element-1-Frame" role="presentation" style="position: relative;" tabindex="0">0.25∘×0.25∘ grid by adapting the Vegetation, Photosynthesis, and Respiration Model (VPRM) to the eastern half of China for the time period from 2005 to 2009; the minimal empirical parameterization of the VPRM-CHINA makes it well suited for inverse modeling approaches. This study diverges from previous VPRM applications in that it is applied at a large scale to China's ecosystems for the first time, incorporating a novel processing framework not previously applied to existing VPRM versions. In addition, the VPRM-CHINA model prescribes methods for addressing dual-cropping regions that have two separate growing-season modes applied to the same model grid cell. We evaluate the VPRM-CHINA performance during the growing season and compare to other biospheric models. We calibrate the VPRM-CHINA with ChinaFlux and FluxNet data and scale up regionally using Weather Research and Forecasting (WRF) Model v3.6.1 meteorology and MODIS surface reflectances. When combined with an anthropogenic emissions model in a Lagrangian particle transport framework, we compare the ability of VPRM-CHINA relative to an ensemble mean of global hourly flux models (NASA CMS – Carbon Monitoring System) to reproduce observations made at a site in northern China. The measurements are heavily influenced by the northern China administrative region. Modeled hourly time series using vegetation fluxes prescribed by VPRM-CHINA exhibit low bias relative to measurements during the May–September growing season. Compared to NASA CMS subset over the study region, VPRM-CHINA agrees significantly better with measurements. NASA CMS consistently underestimates regional uptake in the growing season. We find that during the peak growing season, when the heavily cropped North China Plain significantly influences measurements, VPRM-CHINA models a CO₂ uptake signal comparable in magnitude to the modeled anthropogenic signal. In addition to demonstrating efficacy as a low-bias prior for top-down CO₂ inventory optimization studies using ground-based measurements, high spatiotemporal resolution models such as the VPRM are critical for interpreting retrievals from global CO₂ remote-sensing platforms such as OCO-2 and OCO-3 (planned). Depending on the satellite time of day and season of crossover, efforts to interpret the relative contribution of the vegetation and anthropogenic components to the measured signal are critical in key emitting regions such as northern China – where the magnitude of the vegetation CO₂ signal is shown to be equivalent to the anthropogenic signal.

The changing carbon content of coal consumed in China between 2002 and 2012 is quantified using information from the power sector. The carbon content decreased by 7.7% over this interval, the decrease particularly pronounced between 2007 and 2009. Inferences with respect to the changing carbon content of coal and the oxidation rate for its consumption, combined with the recent information on coal use in China, are employed to evaluate the trend in emissions of CO₂. Emissions are estimated to have increased by 158% between 2002 and 2012, from 3.9 Gt y-1 to 9.2 Gt y-1. Our estimated emissions for 2005 are notably consistent with data reported by China in its “Second National Communication” to the UN (NDRC, 2012) and significantly higher than the estimation published recently in Nature. The difference is attributed, among other factors, to the assumption of a constant carbon content of coal in the latter study. The results indicate that CO₂ emissions of China in 2005 reported by Second National Communication are more reliable to serve as the baseline for China's future carbon commitments (e.g. those in Paris Agreement of the UNFCCC). Discrepancies between national and provincial statistics on coal production and consumption are investigated and attributed primarily to anomalous reporting on interprovincial trade in four heavily industrialized provinces.

pH is an important property of aerosol particles but is difficult to measure directly. Several studies have estimated the pH values for fine particles in North China winter haze using thermodynamic models (i.e., E-AIM and ISORROPIA) and ambient measurements. The reported pH values differ widely, ranging from close to 0 (highly acidic) to as high as 7 (neutral). In order to understand the reason for this discrepancy, we calculated pH values using these models with different assumptions with regard to model inputs and particle phase states. We find that the large discrepancy is due primarily to differences in the model assumptions adopted in previous studies. Calculations using only aerosol phase composition as inputs (i.e., reverse mode) are sensitive to the measurement errors of ionic species and inferred pH values exhibit a bimodal distribution with peaks between −2 and 2 and between 7 and 10. Calculations using total (gas plus aerosol phase) measurements as inputs (i.e., forward mode) are affected much less by the measurement errors, and results are thus superior to those obtained from the reverse mode calculations. Forward mode calculations in this and previous studies collectively indicate a moderately acidic condition (pH from about 4 to about 5) for fine particles in North China winter haze, indicating further that ammonia plays an important role in determining this property. The differences in pH predicted by the forward mode E-AIM and ISORROPIA calculations may be attributed mainly to differences in estimates of activity coefficients for hydrogen ions. The phase state assumed, which can be either stable (solid plus liquid) or metastable (only liquid), does not significantly impact pH predictions of ISORROPIA.

Emissions from power plants in China and India contain a myriad of fine particulate matter (PM2.5, PM≤2.5 micrometers in diameter) precursors, posing significant health risks among large, densely settled populations. Studies isolating the contributions of various source classes and geographic regions are limited in China and India, but such information could be helpful for policy makers attempting to identify efficient mitigation strategies. We quantified the impact of power generation emissions on annual mean PM2.5 concentrations using the state-of-the-art atmospheric chemistry model WRF-Chem (Weather Research Forecasting model coupled with Chemistry) in China and India. Evaluations using nationwide surface measurements show the model performs reasonably well. We calculated province-specific annual changes in mortality and life expectancy due to power generation emissions generated PM2.5 using the Integrated Exposure Response (IER) model, recently updated IER parameters from Global Burden of Disease (GBD) 2015, population data, and the World Health Organization (WHO) life tables for China and India. We estimate that 15 million (95% Confidence Interval (CI): 10 to 21 million) years of life lost can be avoided in China each year and 11 million (95% CI: 7 to 15 million) in India by eliminating power generation emissions. Priorities in upgrading existing power generating technologies should be given to Shandong, Henan, and Sichuan provinces in China, and Uttar Pradesh state in India due to their dominant contributions to the current health risks.